What question did this study set out to answer?

Investigate how methyl substitution on cyclopentene rings influences the pathways of ozonolysis and modulates the chemical reactivity and stability of the resulting ozonides.

August 1, 1994The Journal of Organic Chemistry

Exceptionally Stable Ozonides. Influence of Methyl Substituents on the Course of Cyclopentene Ozonolyses and on the Reactivities of Ozonides

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Authors

HMHerbert MayrLudwig-Maximilians-Universität München JBJanusz BaranUniversité de Lille EWElfriede WillUniversity of Szczecin

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Implication

Experimental study demonstrates exceptional stability in methyl-substituted cyclopentene ozonides, suggesting substituent effects modulate ozonolysis pathways.

Key Points

Investigate how methyl substitution on cyclopentene rings influences the pathways of ozonolysis and modulates the chemical reactivity and stability of the resulting ozonides.
Subjected methyl-substituted cyclopentene derivatives to ozonolysis reactions.
Characterized and evaluated the stability and reactivity profiles of the synthesized ozonide intermediates.
Observed the formation of exceptionally stable ozonides derived from methyl-substituted cyclopentenes.
Demonstrated that the placement and presence of methyl substituents fundamentally alter the course of cyclopentene ozonolyses and suppress ozonide decomposition pathways.

Cite This Study

Mayr et al. (1994) studied this question.

synapsesocial.com/papers/6a712baa6ceb2bbd16e0167b https://doi.org/10.1021/jo00096a059

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Implication

Experimental study demonstrates exceptional stability in methyl-substituted cyclopentene ozonides, suggesting substituent effects modulate ozonolysis pathways.

Exceptionally Stable Ozonides. Influence of Methyl Substituents on the Course of Cyclopentene Ozonolyses and on the Reactivities of Ozonides

Discussion

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Implication

Key Points

Cite This Study

Exceptionally Stable Ozonides. Influence of Methyl Substituents on the Course of Cyclopentene Ozonolyses and on the Reactivities of Ozonides

Discussion

Member takes

Implication

Key Points

Cite This Study

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