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A palladium-containing material based on the new metal-organic framework structure MOF-5/20% calix[4]arene have been synthesized and characterized by physical and chemical methods for the first time. The catalytic activity of the 3% Pd/MOF-5/20% calix[4]arene composite in partial 1,3-cyclohexadiene hydrogenation into cyclohexene is fairly high and is comparable with that of the 5% Pd/C reference catalyst.
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Исаева et al. (2011) studied this question.
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