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A method for C(sp 3 )–C(sp 3 ) cross-coupling of amines is described. Primary amines are converted to 1,2-dialkyldiazenes by treatment with O -nosylhydroxylamines in the presence of atmospheric oxygen. Denitrogenation of the diazenes with an iridium photocatalyst then forges the C–C bond. The substrate scope accommodates a broad latitude of functionality, including heteroaromatics and unprotected alcohols and acids.
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Steiniger et al. (2023) studied this question.
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