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From leaves of Engelhardtia chrysolepis, a Chinese sweet tea, a set of the diastereomers of astilbin (3-O-α-L-rhamonosyl-(2R, 3R)-taxifolin) was isolated together with eucryphin and quercitrin. Of these isomers, 3-O-α-L-rhamnosyl-(2S, 3S)-taxifolin (neoastilbin) was found to taste sweet. This is the first discovery of the sweetness of a dihydroflavonol glycoside.
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Kasai et al. (1988) studied this question.
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