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The palladium‐catalyzed aerobic oxidative kinetic resolution of key pharmaceutical building blocks is described. Substrates investigated are relevant to the enantioselective preparation of Prozac ® , Singulair ® , and the promising hNK‐1 receptor antagonist from Merck. The latter provides the most selective aerobic oxidative kinetic resolution yet described.
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Caspi et al. (2004) studied this question.
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