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December 29, 2003Angewandte Chemie

Palladium‐Catalyzed Oxidative Kinetic Resolution with Ambient Air as the Stoichiometric Oxidation Gas

Jeffrey T. Bagdanoff Brian M. Stoltz

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Abstract

Luft reicht aus, um die hoch enantioselektive Oxidation sekundärer Alkohole mit Palladium(II) und Spartein bei Raumtemperatur in nichtentflammbaren Solventien zu vermitteln. Die Untersuchung von Wasserstoffbrücken bildenden Lösungsmitteln und ihrer Fähigkeit, Halogenide zu solvatisieren, führte zu einem neuartigen Protokoll für die hoch enantioselektive oxidative kinetische Racematspaltung von sekundären Alkoholen.

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Bagdanoff et al. (2003) studied this question.

synapsesocial.com/papers/6a71a24987f9210571284c28 https://doi.org/10.1002/ange.200352444

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