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Physically self-assembled microstructures can be realized by utilizing the stress relief process in buckling that usually leads to the formation of random wrinkles. This physical self-assembly occurs when the wrinkle formation is guided by a periodic pattern on an elastomeric mold that is simply placed on the surface of a bilayer of metal on polymer, which is then heated above its glass-transition temperature (see Figure and inside cover).
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Yoo et al. (2002) studied this question.
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