Laboratory study demonstrates decarbonylative cross-coupling of azoles and aromatic esters via palladium catalysis, highlighting an expanded substrate scope compared to nickel catalysts.
A decarbonylative C-H coupling of azoles and aromatic esters by palladium catalysis is described. Our previously reported Ni-catalyzed C-H coupling of azoles and aromatic esters has a significant drawback regarding the substrate scope. Herein, we employ palladium catalysis instead of nickel, resulting in a broader substrate scope in terms of azoles and aromatic esters.
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Matsushita et al. (2018) studied this question.
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