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We developed a new Ti-alloyed Al-oxide (TiAlO/sub x/) as an insulating barrier for magnetic tunnel junction (MTJ) that has a lower resistance /spl times/ area (RA) value and bandgap than when Al-oxide is used. The RA value of the MTJs dropped from 9.5 to 0.69 M/spl Omega/ /spl mu/m/sup 2/ as the Ti concentration increased to 5.33 at.%. The lower RA value of the MTJs resulted from the bandgap reduction; the extra bands were composed mainly of Ti-3d orbitals in the bandgap. In addition, a significant tunneling magnetoresistance (TMR) value of 20% was maintained after annealing at 450/spl deg/C and a higher bias voltage (V/sub h/) and breakdown voltage (V/sub B/) of 681 mV and 1.35 V, respectively, were obtained in the MTJs with a 5.33 at.% TiAlO/sub x/ barrier. These results were closely related to the enhanced microstructural and interfacial quality of the Ti-Al alloy film in the preoxidation state.
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Song et al. (2005) studied this question.
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