Experimental study demonstrates synthesis of stable beta-phosphorylated ring nitroxides using aminomercuration, suggesting distinct structural geometry through spectroscopy and modeling.
A series of stable beta-phosphorylated five membered ring nitroxides was prepared by intramolecular aminomercuration of alkenyl alpha-aminophosphonates. The structure of these nitroxides was deduced from their 13C and 31P coupling constants and from force field calculations.
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Dembkowski et al. (1993) studied this question.
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