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Pentacoordinate triethylammonium bis (catecholato) alkenylsiliconates, readily prepared from alkenyltrialkoxysilane, catechol, and triethylamine, react with aryl iodides, vinylic iodides and aryl triflates catalyzed by a palladium complex to give the corresponding cross-coupled products in a stereospecific mode.
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Hosomi et al. (1988) studied this question.
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