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Stuck on you: Preferred (110) and (001) orientation of enantiopure [{Zn2((+)cam)2(dabco)}n] ((+)cam=(1R,3S)-(+)-camphoric acid, dabco=1,4-diazabicyclo(2.2.2)octane) thin films can be controlled by carboxylate and pyridyl groups on self-assembled monolayers (SAMs). With a quartz crystal microbalance, the enantioselective adsorption of enantiomeric hexanediol pairs by enantiopure surface-attached metal–organic frameworks (SURMOF) [Zn2((±)cam)2(dabco)] pairs can be demonstrated (see picture).
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Liu et al. (2011) studied this question.
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