We present the first soft x-ray-emission spectra for solid Kr (4p-3d) and Xe (5p-4d) that are free of complicating satellite spectra. Monochromatic synchrotron-radiation excitation is used to suppress the satellites. The data are analyzed to determine the P3/2 bandwidth for both elements; these results are compared with both photoemission data and available theoretical calculations. Bandwidths are found to be larger than those predicted by most electronic structure calculations.
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Jia et al. (1991) studied this question.
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