The bonding in heteropolyhedral compounds of the closo-borane type is discussed for “As2(AlCp*)3” clusters, whose molecular structure has been characterized by X-ray crystallography (framework shown on the right). Quantum chemical calculations on several trigonal-bipyramidal EE structures revealed the mode of bonding for a variety of ligands (Cp* = C5Me5; EIII: Group 13 element, EV: Group 15 element).
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Hänisch et al. (1996) studied this question.
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