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The reactions of silyl-substituted homoallyl alcohols with aryl halides under palladium catalysis result in regiospecific and stereoselective allyl transfer from the alcohols to aryl halides, offering modular synthesis of ( E )-3-aryl-1-alkenyl-, ( E )-1-aryl-2-alkenyl-, and optically active ( E )-1-aryl-2-butenylsilanes.
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Hayashi et al. (2007) studied this question.
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