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Palladium(II) complexes containing bidentate cyclometalated C∼N chelating ligands are shown to react with PhI NTs at room temperature to insert “NTs” into the Pd−C bond. This “NTs” insertion reaction has been applied to palladacyclic complexes of azobenzene, benzo[ h ]quinoline, and 8-ethylquinoline. The newly aminated organic ligands can be liberated from the metal center by protonolysis with trifluoroacetic acid or HCl.
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Dick et al. (2007) studied this question.
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