Pressure-volume-temperature relations for water at the depth of the magma chamber at 21 degrees N on the East Pacific Rise suggest that the maximum subsurface temperature of the geothermal fluid is about 420 degrees C. Both the chemistry of the discharging fluid and thermal balance considerations indicate that the effective water/rock ratios in the geothermal system are between 7 and 16. Such low ratios preclude effective metal transport at temperatures below 350 degrees C, but metal solubilization at 400 degrees C and above is effective even at such low ratios. It is proposed that the 420 degrees C fluid ascends essentially adiabatically and in the process expands, cools, and precipitates metal sulfides within the upper few hundred meters of the sea floor and on the sea floor itself.
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James L. Bischoff (1980) studied this question.
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