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May 25, 2010Angewandte Chemie

Cleavage of the SnSn Multiple Bond in a Distannyne by Cyclooctatetraene: Formation of the π‐Bound Inverse Sandwich Complex [(Ar′Sn)₂(μ₂‐η²:η³‐cot)]

Owen T. Summerscales Xinping Wang Philip P. Power

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Abstract

Wenn ein Distannin Cyclooctatetraen aktiviert, kommt es zur vollständigen Spaltung der SnSn-Bindung und zur Bildung eines inversen Sandwich-Komplexes mit einem π-gebundenen aromatischen planaren C8H8-Ring (siehe Schema; Ar′ = C6H3-2,6-(C6H3-2,6-iPr2)2).

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Summerscales et al. (2010) studied this question.

synapsesocial.com/papers/6a7361bcdea3f1d1ad5662c0 https://doi.org/10.1002/ange.201001276

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