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The chemistry of formation of iridium clusters from mononuclear iridium diethylene complexes anchored in dealuminated Y zeolite, and their subsequent breakup—all including changes in the metal–metal, metal–support, and metal–ligand interactions—is demonstrated by time-resolved EXAFS, XANES, and IR spectroscopy.
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Uzun et al. (2008) studied this question.
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