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December 1, 1998Nucleosides and Nucleotides

Novel Lewis Acid-Catalyzed Rearrangement of a Sugar-Base Hybrid to Afford an Anhydronucleoside

Michael E. Jung Claire Castro Saeed I. Khan

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Abstract

Treatment of the sugar-base hybrid 9 with boron trichloride at low temperature for 40 h affords the 6,3′-anhydro-2′-deoxyuridine 10 in 40% yield (80% based on recovered 9) via a novel structural rearrangement.

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Jung et al. (1998) studied this question.

synapsesocial.com/papers/6a7376ff2278f6c662a72a19 https://doi.org/10.1080/07328319808004325

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