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November 24, 2006Chemical Communications

π-Bonding encapsulation in aryl-substituted lanthanide selenolates: monomeric compounds with apparent low-coordinate metal atoms

Sven‐Oliver Hauber M. Niemeyer

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Abstract

Reaction of LnCl3 with KSeAr* in thf afforded the unsolvated, alkane-soluble complexes LnCl(SeAr*)2 (Ln = Nd, Pr; Ar* = 2,6-Trip(2)C(6)H(3); Trip = 2,4,6-iPr(3)C(6)H(2)) in which the rare-earth metal cations show additional eta6-pi-coordination by two flanking arene rings.

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Hauber et al. (2006) studied this question.

synapsesocial.com/papers/6a7392dd61762fa209a72f99 https://doi.org/10.1039/b612182a

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Synapse has enriched 5 closely related papers on similar clinical questions. Consider them for comparative context:

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