Palladium can tailor fullerenes: Palladium catalysts enable a number of C-H bond transformations of organo(hydro)fullerene. In addition to anticipated coupling reactions (C-H bond allylation and arylation), an unexpected new C-H bond dimerization reaction and C-C bond-cleavage reaction were also uncovered.
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Nambo et al. (2009) studied this question.
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