Potential energy curves for the X 1Σ+, A 1Σ+, and B 1π states of LiH have been calculated by the Rydberg-Klein-Rees method. The results are in agreement with curves previously obtained by Crawford and Jorgensen and by Rosenbaum using different methods. As a check, the somewhat peculiar curve for the A 1Σ+ state has also been calculated for LiD, and agrees with the LiH curve to about one percent. The curves obtained theoretically by Karo and Olson for the X 1Σ+ and A 1Σ+ states are only in fair agreement with the experimental results.
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Fallon et al. (1960) studied this question.
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