Synthetic methodology study demonstrates copper-catalyzed fluorodesulfurization using DAST at room temperature, highlighting high efficiency and broad functional group tolerance for ether synthesis.
An efficient CuI-catalyzed fluorodesulfurization for the synthesis of monofluoromethyl aryl ethers using DAST at room temperature has been developed. This approach exhibits a good functional group tolerance, a broad substrate scope, and a high synthesis efficiency.
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Geng et al. (2017) studied this question.
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