Copper‐Catalyzed Borylation of α‐Alkoxy Allenes with Bis(pinacolato)diboron: Efficient Synthesis of 2‐Boryl 1,3‐Butadienes

Something solid to build on: 2-Boryl 1,3-butadienes with various substitution patterns were formed in good to high yields in a copper-catalyzed borylation of α-alkoxy allenes with bis(pinacolato)diboron (see scheme; Bn=benzyl, pin=pinacolate, L is an N-heterocyclic carbene ligand). The products were found to be useful intermediates for the synthesis of cyclic vinyl boranes, α,β-unsaturated ketones, and functionalized multisubstituted dienes.