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Aminopyridine manganese complexes [LMn(II)(OTf)(2)] having a similar coordination topology catalyze the oxidation of unactivated aliphatic C-H groups with H(2)O(2), demonstrating excellent efficiency (up to TON = 970), site selectivity, and stereospecificity (up to >99%).
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Ottenbacher et al. (2012) studied this question.
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