Ion-mobility mass spectrometry of complexes of nickel and acetonitrile

Mono- and dications of microsolvated nickel complexes of acetonitrile are probed by means of ion-mobility mass spectrometry. Specifically, the complexes [(CH 3 CN) n Ni] + , [(CH 3 CN) n Ni] 2+ , [(CH 3 CN) n NiOH] + , and [(CH 3 CN) n NiCl] + ( n = 0–6) are compared to each other and their reactions with background water are probed. In general, the arrival times of the ions in the ion-mobility experiment linearly increase with the mass-to-charge ratio, but for the smaller, more reactive complexes, the arrival times are notably larger than expected from their mass. This effect is attributed to the markedly larger reactivity of these particular ions, as reflected in both charge-separation processes as well as adduct formation upon interaction with background water.