General and Controllable Synthesis Strategy of Metal Oxide/TiO2 Hierarchical Heterostructures with Improved Lithium-Ion Battery Performance

We demonstrate a simple, efficient, yet versatile strategy for the synthesis of novel hierarchical heterostructures composed of TiO(2) nanofiber stem and various metal oxides (MOs) secondary nanostructures, including Co(3)O(4), Fe(2)O(3), Fe(3)O(4), and CuO, by advantageously combining the versatility of the electrospinning technique and hydrothermal growth method, for which the controllable formation process and possible formation mechanism are also investigated. Moreover, as a proof-of-concept demonstration of the functional properties of these hierarchical heterostructures, the Co(3)O(4)/TiO(2) hierarchical heterostructures are investigated as the lithium-ion batteries (LIBs) anode materials for the first time, which not only delivers a high reversible capacity of 632.5 mAh g(-1) and 95.3% capacity retention over 480 cycles, but also shows excellent rate capability with respect to the pristine TiO(2) nanofibers. The synergetic effect between Co(3)O(4) and TiO(2) as well as the unique feature of hierarchical heterostructures are probably responsible for the enhanced electrochemical performance.