Electrochromic devices based on soluble and processable dioxythiophene polymersElectronic supplementary information (ESI) available: details of the synthesis of PProDOT(CH2OC18H37)2 and PProDOT(CH2OEtHx)2 and their polymerization. See http://www.rsc.org/suppdata/jm/b3/b306365h/

Reflective and absorptive/transmissive polymer electrochromic devices (ECDs) composed of spray-coated films of poly(3,3-bis(octadecyloxymethyl)-3,4-dihydro-2H-thieno[3,4-b][1,4]dioxepine) (PProDOT(CH2OC18H37)2) and poly(3,3-bis(2-ethylhexyloxymethyl)-3,4-dihydro-2H-thieno[3,4-b][1,4]dioxepine) (PProDOT(CH2OEtHx)2) layers as cathodically coloring polymers and poly(3,6-bis(2,3-dihydrothieno[3,4-b][1,4]dioxin-5-yl)-9-methyl-9H-carbazole) (PBEDOT-NMeCz) as the anodically coloring polymer have been constructed and evaluated. These devices exhibit low switching voltages (±1.2 V), high visible contrast values, sub-second switching times, and high switching stability in atmospheric conditions. The reflective ECD comprising PProDOT(CH2OEtHx)2 as the active layer demonstrates an unusual electrochromic behavior. By regulating the applied voltage, a high reflectance contrast of greater than 70% ΔT was achieved in the NIR region (2 µm) without any noticeable color change of the device.