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A procedure for the production of N-heterocyclic carbene–boryl radicals (NHC-BH 2 • ) upon visible light irradiation under soft conditions is presented. New acridine orange (dye)/diphenyl disulfide/NHC–BH 3 and dye/sulfonium salt/NHC–BH 3 three-component initiating systems are introduced for the efficient visible light photopolymerization of trimethylolpropane triacrylate. The new systems could be extendend to polymerization reactions in water (hydroxyethyl acrylate and hydroxyethyl methyl acrylate), which proceeded with strongly improved polydispersity. The chemical mechanisms are investigated through EPR and photolysis experiments.
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Telitel et al. (2012) studied this question.
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