Answers are grounded in this paper and cite their sources.
MOFs come alive: The combination of gas-adsorption experiments at various temperatures with an osmotic thermodynamic model produced a generic temperature–loading phase diagram that displays unexpected re-entrant behavior. The breathing effect in the metal–organic framework MIL-53(Al) is predicted to be general and should be observed over a limited temperature range regardless of the guest adsorbate.
No takes yet. Share an insight, caveat, or question.
Boutin et al. (2009) studied this question.
Synapse has enriched 10 related papers. Consider them for comparative context: