Effect of short-term sulphate contamination on lime-stabilized expansive soil

Lime stabilization is an age-old technique for controlling the swell-shrink characteristics of the expansive soil. However, the presence of sulphate in the expansive soils renders the lime stabilization ineffective due to the formation of detrimental compounds – ettringite and thaumasite. The formation of these detrimental compounds can be counteracted by treatment with low-calcium or non-calcium based stabilizers. However, there is a possibility of sulphate contamination post lime stabilization through external sources. Therefore, the present study brings out the effect of short-term sulphate contamination on lime-stabilized expansive soil using sodium sulphate solution. To achieve this objective, the lime-stabilized expansive soil was cured for 1, 7 and 28 days, and subsequently mixed with sulphate solutions of 5000–20,000 ppm concentration and allowed to equilibrate for 1 day. The experimental results showed that the sulphate contamination had a significant effect on the soil structure, physico-chemical and index properties of lime-stabilized soil. The mechanism governing the deterioration of the stabilized soil depended on the curing period of lime-stabilized soil prior to contamination with sulphate. Short-term sulphate contamination of lime-stabilized soil cured for 1 and 7 days resulted in highly flocculated structure, whereas the lime-stabilized soil cured for 28 days resulted in the formation of ettringite. This is evidenced with the aid of Scanning Electron Microscopy (SEM) images, X-ray diffraction (XRD) and Energy Dispersive X-Ray Analysis (EDAX). It can be concluded from this study that the ettringite formation occurs even after the formation of pozzolanic compounds in lime-stabilized soil.