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The d bands of Zn and Cd have been unambiguously located by photoelectron spectroscopy using 40.81-eV radiation. In Zn a single peak due to the 3d3/2,5/2 band of half-width 1.1 eV is found 9.5 eV below Fermi level, while for Cd, the 4d3/2,5/2 doublet is resolved at 10.2 and 11.1 eV below the Fermi level. The relevance of these results for band-structure calculations and for the interpretation of related optical and characteristic energy-loss experiments is discussed.
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Poole et al. (1973) studied this question.
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