About 22000 times faster than the decomposition of 1, 2 decomposes to form the corresponding olefin and cyclic phosphinate [Eq. (a)]; a remarkable solvent effect is observed for the reaction of 2. Lithiation and subsequent methoxycarbonylation of 1 provided colorless needles of 2.
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Kawashima et al. (1993) studied this question.
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