The paramagnetic resonance spectrum of Gd³⁺ in LaCl₃·{}7H₂O was measured and found to agree quite well with a spin Hamiltonian with dominant coefficients b₂⁰=±0.0131 cm^-1, b₂²=∓0.0075 cm^-1 at room temperature, and b₂⁰=±0.0099 cm^-1, b₂²=∓0.0115 cm^-1 at liquid air temperature.
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Weger et al. (1958) studied this question.
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