The HRP-catalyzed oligomerization of cinnamoyl-hydroquinone-ester and cinnamoyl-4-hydroxyanilide led to the formation of soluble polyphenols. The oligomers were synthesized in water/1,4-dioxane and in water/acetone mixtures and characterized by NMR, FTIR and SEC. Upon UV-treatment of the homogenous films the polyphenols were crosslinked due to [2+2]-cycloadditions of the cinnamoyl functions.
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Reihmann et al. (2000) studied this question.
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