Temperature-driven phase transitions of V 1− x Cr x O 2 (with x = 0.00 and 0.007) have been studied by means of vanadium K -edge X-ray absorption spectroscopy between 50 and 350 K. X-ray absorption near-edge structure (XANES) reveals the electronic changes occurring across the metal-insulator transition at ∼350 K. Extended X-ray absorption fine structure (EXAFS) spectroscopy enlightens the modification occuring to the VO 6 octahedra across the different monoclinic (M1, M2, M3) and rutile (R) structures. The EXAFS results provide a complete local structural characterization of the competing lower-symmetry phases of the V 1− x Cr x O 2 (with x = 0.00 and 0.007) and shed light on the major role of lattice relaxation energy in the degradation properties of several devices based on the metal-insulator transition.
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Marini et al. (2013) studied this question.
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