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Single crystal EPR spectra of tris(octamethylpyrophosphoramide) copper (II) perchlorate have been obtained at 90 °K. The results are correlated with x-ray structural data and evidence is presented in support of a model in which three g tensors are related by the trigonal axis of the unit cell. The model is consistent with the dynamic-static Jahn-Teller theory proposed by Abragam and Pryce which assumes the presence of three mutually perpendicular tetragonal distortions of equal energy.
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Koch et al. (1973) studied this question.
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