The kinetics of the gamma‐radiation induced free radical reactions in carbon tetrachloride solutions of 2,3‐dimethylbutane (DMB) were studied in the temperature range 32–118 °C. The kinetics of the following reactions were measured: and the following rate constants expression was obtained: . The activation energy and the A factor obtained are in good agreement with the values obtained at the gaseous phase, considering the activation energy for self‐diffusion of CCl 4 .
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Alfassi et al. (1980) studied this question.
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