Thermal and Mechanical Behavior of Carbon‐Nanotube‐Filled Latex

Summary: Composite films were prepared from a mixture of poly(vinyl acetate) latex and SWNTs. SEM images reveal a segregated SWNT network that grows heavier with increasing concentration. Nanotube segregation is the result of excluded volume created by the much larger polymer particles in the latex. Thermal conductivity exhibits a sharp rise with increasing quantity of nanotubes, although the maximum value is only 10% greater than that of the polymer matrix due to large thermal interface resistance. Storage modulus exhibits a peak and subsequent drop due to pore formation. In the absence of porosity, the Halpin‐Tsai model accurately predicts the composite modulus at 25 °C. The segregated network improves the composite modulus above T g by nearly an order of magnitude with only 2 wt.‐% SWNT. Schematic illustration of a segregated network of carbon nanotubes. magnified image Schematic illustration of a segregated network of carbon nanotubes.