Chemical transformations occurring during melt processing of polymers such as polyethylene are described in terms of kinetics of relevant reactions. A model is developed which takes into consideration; chemical, thermal, and mechanical effects, autocatalitic reactions, as well as the role of inhibitors. The calculated predictions are verified with the experimental data. The results are used to make recommendations for the improvements of the melt extrusion process.
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El'darov et al. (1995) studied this question.
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