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October 23, 1999Chemical Reviews

ortho-Arene Cyclynes, Related Heterocyclynes, and Their Metal Chemistry

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Authors

WYWiley J. YoungsUniversity of AkronCTClaire A. TessierUniversity of AkronJBJ. D. BradshawWake Forest University

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Implication

Review demonstrates synthetic pathways and coordination behaviors of ortho-arene cyclynes with transition metals, highlighting their utility as versatile macrocyclic ligands.

Key Points

  • Summarize the synthesis, structural features, and transition metal coordination chemistry of ortho-arene cyclynes and related heterocyclynes.
  • Review of published chemical literature detailing synthetic pathways to ortho-arene cyclynes and heterocyclynes.
  • Evaluation of spectroscopic properties, structural characterizations, and crystallographic analysis of cyclyne metal complexes.
  • Modular synthetic methods yield rigid macrocyclic systems containing alternating aromatic subunits and acetylenic linkages.
  • Cyclyne architectures function as multidentate ligands capable of coordinating diverse transition metal centers into stable organometallic frameworks.

Cite This Study

Youngs et al. (1999) studied this question.

synapsesocial.com/papers/6a767ecb60d5430a442957cahttps://doi.org/10.1021/cr9902446
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