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The use of the tris(alkylamido)phosphate OP[N(H)tBu]3 as an in situ source of the templating agent [tBuNH3]+ produces the copper halide chain {[tBuNH3]2[Cu3(mu3-OH)(mu2-H2O)Cl7]}n (1) in a solvothermal process; the novel antiferromagnetically coupled trinuclear fragment Cu3(OH)(H2O)Cl7 is the building block in the polymeric anion in .
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Chivers et al. (2005) studied this question.
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