Direct analysis of polar solutes by supercritical fluid chromatography (SFC) has been somewhat limited because the mobile phases in common use are all relatively nonpolar. Derivatization is demonstrated as a viable means for facilitating the SFC separation of sugars. Oligo‐ and polysaccharides containing up to 18 glucose units are completely resolved by capillary SFC.
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Chester et al. (1986) studied this question.
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