Synapse
⌘+K
Synapse
PulseExploreClubsResearchersJournals
Instagram
HomeClubsExplore
August 10, 2026Chemistry of MaterialsOpen Access

ElectronicStructure of Cu-Phthalocyanine Metal–OrganicFramework

View Full Paper
Ask AI
Bookmark
Share

Authors

MIMomoka IsobeKOKenichi OzawaJTJun’ya Tsutsumi

Discussion

Loading...

Member takes

Overview

Investigates the electronic properties of CuPc-MOF, suggesting potential applications in conductive materials.

Key Points

  • The research aims to investigate the electronic properties of Cu-phthalocyanine metal-organic frameworks (CuPc-MOF) and understand their structural significance.
  • Synthesized CuPc-MOF using the molten-salt method with ZnCl2 as the flux.
  • Conducted X-ray diffraction and transmission electron microscopy to analyze the crystal structure.
  • Utilized density functional theory (DFT) calculations to assess electronic band structure and density of states.
  • DFT calculations indicated that CuPc-MOF is metallic with energy bands showing large dispersion, contrary to experimental outcomes.
  • Optical energy gap measurement showed CuPc-MOF has an energy gap of 0.31 eV, suggesting it is nonmetallic.
  • Electrical measurements demonstrated that CuPc-MOF exhibits higher electrical conductivity than typical organic semiconductors.

Cite This Study

Isobe et al. (2026) studied this question.

synapsesocial.com/papers/6a797d3a9c20a9bbd318478ahttps://doi.org/10.1021/acs.chemmater.6c01551
View Full Paper
Ask AI
Bookmark
Share

Also Consider

Synapse has enriched 5 closely related papers on similar clinical questions. Consider them for comparative context:

  1. 1Electronic structure of Fe-phthalocyanine metal–organic framework2026 · 1 citations
  2. 2Synthesis and Characterization of Highly Conductive Cobalt Phthalocyanine‐Based Metal–Organic Framework2026
  3. 3Benzenehexol‐Based 2D Conjugated Metal–Organic Frameworks with Kagome Lattice Exhibiting a Metallic State2024 · 3 citations
  4. 4Band engineering in two-dimensional porphyrin- and phthalocyanine-based covalent organic frameworks: insight from molecular design2024 · 2 citations
  5. 5Cocrystals, Mixed Films, and Heterostructures Based on Metal Phthalocyanines: Structures, Intermolecular Interactions, and Functional Properties (Review)2026