Electron-reservoir behavior, the formation of RhI/RhII mixed-valent species, and the separation of redox processes and thus “communication” between individual reaction centers were established in a first systematic study of the ligand-mediated coupling of two equivalent “chemical” redox (ECE) reaction centers (E = electron transfer, C = chemical step (here dissociation of chloride); see scheme on the right, Cp* = C5Me5, L = multidentate ligand).
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Kaim et al. (1997) studied this question.
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