What question did this study set out to answer?

To assess the efficacy of nitrosonium salts prepared from nitroxides as selective oxidizing agents for diverse organic functional groups.

January 1, 1988HeterocyclesOpen Access

Prganic Nitrosonium Salts as Oxidants in Organic Chemistry

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Authors

JBJames M. BobbittUniversity of Connecticut JBJames M. BobbittUniversity of Connecticut CFCecil L. Flores

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Implication

Chemical synthesis study demonstrates the utility of nitroxide-derived nitrosonium salts for functional group oxidations, highlighting versatile applications in organic chemistry.

Key Points

To assess the efficacy of nitrosonium salts prepared from nitroxides as selective oxidizing agents for diverse organic functional groups.
Generated nitrosonium salts via the oxidation of precursor nitroxyl radicals.
Subjected alcohols, primary amines, ketones, and phenols to oxidation using the synthesized nitrosonium reagents.
Nitrosonium salts successfully oxidized alcohols to corresponding aldehydes or ketones and primary amines to aldehydes or nitriles.
Substrate reactions converted ketones into alpha-diketones and transformed phenols into quinones.

Cite This Study

Bobbitt et al. (1988) studied this question.

synapsesocial.com/papers/6a7bb3dfc06c4f060a75d898 https://doi.org/10.3987/rev-87-373

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Implication

Chemical synthesis study demonstrates the utility of nitroxide-derived nitrosonium salts for functional group oxidations, highlighting versatile applications in organic chemistry.

Prganic Nitrosonium Salts as Oxidants in Organic Chemistry

Discussion

Member takes

Implication

Key Points

Cite This Study

Prganic Nitrosonium Salts as Oxidants in Organic Chemistry

Discussion

Member takes

Implication

Key Points

Cite This Study

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