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We report the design and synthesis of two Co2+ and Zn2+ phthalocyanine (PC)-based redox active metal-organic conjugated microporous polymers (MO-CMP), CoCMP and ZnCMP, respectively, obtained by a Schiff base condensation reaction. CoCMP, where Co2+ is stabilized by N4-coordination of PC, has shown stable and efficient electrocatalytic activity towards the OER with a low overpotential of 340 mV.
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Singh et al. (2018) studied this question.
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