More Mn: New perovskite oxides (In1−yMny)MnO3 (1/9≤y≤1/3, see picture) were prepared by using a high-pressure technique. The A site is doped with Mn2+ ions, and (In1−yMny)MnO3 is similar to (Lu1−yCay)MnO3. The B-site-ordered structure is realized through the ordering of Mn3+ and Mn4+ ions. Materials with y≤0.25 demonstrate spin-glass-like properties, while (In2/3Mn1/3)MnO3 shows magnetic properties typical for canted antiferromagnets.
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Belik et al. (2010) studied this question.
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