Conductivities of Binary Mixtures of Ionic Liquids with Polar Solvents

Data for the conductivity, κ, of selected binary mixtures of the ionic liquids [emim][BF 4 ], [bmim][BF 4 ], [bmim][PF 6 ], [bmim][DCA], and [hmim][BF 4 ] with polar solvents (water, propylene carbonate, dimethylsulfoxide, methanol, dichloromethane) at 25 °C are reported. Additionally, mixture densities, ρ, were determined to convert κ into molar conductivity, Λ. The obtained results were fitted by appropriate interpolation formulas. Where possible, data were compared with information from the literature. Electrode polarization and sample purity, including [BF 4 − ] hydrolysis, were considered as possible sources of errors in κ. The effect of viscosity on the accuracy of ρ and thus Λ was checked.